Reversible Dissociation of a Dialumene**
نویسندگان
چکیده
Dialumenes are neutral AlI compounds with Al=Al multiple bonds. We report the isolation of an amidophosphine-supported dialumene. Our X-ray crystallographic, spectroscopic, and computational DFT analyses reveal a long extreme trans-bent bond low dissociation energy order. In solution, dialumene can dissociate into monomeric species. Reactivity studies two modes reaction: as or aluminyl monomers.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202111385